Capturing high pressures in diamond capsules - Drs. Zhidan Zeng and Charles Zeng
AUGUST 17, 2022
Preservation of the high-pressure states of materials at ambient conditions is a long-sought-after goal for fundamental research and practical applications. A team of scientists led by Drs. Zhidan (Denise) Zeng, Qiaoshi Zeng, and Ho-Kwang Mao from the Center for High Pressure Science and Technology Advanced Research (HPSTAR) and Prof. Wendy Mao from Stanford University report an innovative breakthrough where they were able to maintain the extraordinary properties of high-pressure materials in free-standing, nanostructured diamond capsules without the support of traditional bulky pressure vessels. Their work was recently published in Nature.
Modern technology is built upon access to materials with suitable physical and chemical properties that can be used to perform specific functions in various devices. Technological advances, therefore, are often dictated by the development of superior materials with desirable properties. High pressure can drastically alter or tune properties of all materials, thus providing a fertile ground for discovering novel materials with extremely favorable properties. The caveat is, however, that the favorable properties often only exist under pressure when the sample remains in the bulky high-pressure vessel, limiting scientific investigation and potential applications. For the past century, scientists have tried to overcome this difficulty. They succeeded only in “quenchable” phases, where novel materials synthesized at high pressure retain their favorable properties after releasing pressure. A well-known example is the high-pressure conversion of ordinary carbon into diamond which is able to keep its brilliance and other exceptional properties after retrieving at ordinary pressures. Unfortunately, such successful examples of quenchable phases are extremely rare, largely rendering high-pressure materials studies of only academic interest with little practical value in the ambient environment.
The HPSTAR and Stanford research group developed a novel approach that has demonstrated the ability to quench even tenuous gases and preserve their high-pressure properties. They compressed glassy carbon, an amorphous form of porous carbon, together with argon gas to 50 gigapascals -- about 500,000 times atmospheric pressure, and heated the sample to 3,320 degrees Fahrenheit. The glassy carbon that is initially impermeable to gases at ordinary conditions absorbs argon like a sponge at high pressures. The application of high pressure and temperature conditions converts the carbon into diamond and traps the now solid, high-pressure argon in its pores. The resulting sample that is retrieved at ambient conditions behaves like a nanocrystalline diamond composite with numerous isolated pores that represent like tiny diamond capsules filled with argon. The residual pressure preserved in the argon by the diamond capsule is as high as 22 gigapascals – about 220 times the pressure at the bottom of the Mariana Trench. Better yet, the pressurized argon sample is sealed in by only nanometer-thick diamond skins allowing its extraordinary properties to be accessible by modern analytical probes that require near vacuum environments like electron microscopy.
“We directly observe many nanometer-sized high-pressure argon grains encapsulated in the nano-diamond matrix by high-resolution transmission electron microscopy; thus, we named them nanostructured diamond capsules (NDCs),” explained Dr. Denise Zhidan Zeng, the lead author of this work. “One of the keys to realizing the concept of NDCs is choosing the right carbon precursor which is sp2 bonded and has pre-existing enclosed sample chambers. This is obviously by no means limited to glassy carbon. Therefore, a variety of crystalline, amorphous, and low-dimensional carbon allotropes could potentially be used as the precursor carbon as well, offering a wide range of capsule materials for optimization of the NDC process,” explained Dr. Denise Zhidan Zeng.
“Using multiple complementary diagnostic probes to obtain consistent results features the modern matter research. However, in-situ high-pressure studies have always required high-penetrating probes such as hard x-ray due to the thick high-pressure vessel walls involved. Therefore, many powerful and versatile probes, such as electron microscopy and vacuum ultraviolet to soft x-ray spectroscopy, that require a near vacuum environment, unfortunately, remain incompatible with high-pressure science and technology. This has severely hindered our efforts to understand many high-pressure materials,” said Dr. Qiaoshi Zeng. “By synthesizing NDCs, we offer a general method to remove bulky pressure vessels while maintaining the high-pressure conditions and therefore the high-pressure behavior in our samples. We can now employ almost all the modern diagnostic probes to obtain detailed information of the atomic/electronic structures, compositions, and bonding nature of materials at high pressures inside NDCs, including various techniques based on transmission electron microscopy. We are excited about the possibility that an approach based on NDCs will bring high-pressure explorations on par with conventional condensed-matter investigations and applications.”
“Beyond the gases that we explored in our study, we also expect the concept of NDCs to be generally applicable to various solid samples,” said Prof. Wendy Mao. “Moreover, NDC samples are in principle cumulative with the potential for unlimited, multiple syntheses, thus removing the limitation where high-pressure phenomena only exist in a tiny sample inside a large pressure chamber. Therefore, our work demonstrates the first, critical step toward the grand challenge of high-pressure materials applications for previously unquenchable phases.”
This work involves many other co-authors from HPSTAR in China and Argonne national laboratory in USA. The financial support is from the National Key Research and Development Program of China (2019YFA0708502, 2018YFA0703400, and 2021YFA0718900) and National Natural Science Foundation of China (51871054, and U1930401).
Caption: A perspective cartoon drawing of nanostructured diamond capsules (NDCs) with high-pressure argon nanodomains embedded in the matrix. Modern diagnostic probes such as hard/soft x-ray, ultraviolet-visible-infrared light, electron, and neutron beams are all applicable to the NDCs samples for investigations.
"将高压下产生的各种新奇物理、化学现象保留到常压”一直是基础研究和材料应用领域的一个长期追求的梦想。最近，北京高压科学研究中心曾桥石研究员带领的研究团队朝着这一梦想取得了里程碑式突破 ¾ 他们制备了一种金刚石构成的纳米压力舱复合材料，能够把物质的高压态永久地封存在其中，成功摆脱了传统压力装置的物理束缚而能如普通材料一样在常压条件下独立存在，扫除了高压态物质基础研究和应用的一个主要障碍。这一创新性成果于8月17日在国际顶级学术期刊《自然》上发表。