High Pressure Chemistry Group (HPChem) Research

The synthesis of materials with low-Z under extreme conditions

◆ Controllable synthesis of multi-dimensional carbon materials by physical means such as high pressure

We use high pressure combined with high temperature, light and other conditions to synthesize multi-dimensional carbon-and nitrogen-based materials from small molecules such as diamond nanowires, graphane, nanographite ribbons, etc.. Furthermore, we will also try to study the control laws of related reactions, and establish the systematical method of synthezing carbon- and nitrogen-based materials under extreme conditions. This will provides a high-pressure solution for the atomic-level controllable synthesis of material structures.

◆Synthesis of the functional material under high pressure

High pressure is an effective means to synthesize high-density modified polymer materials. We will try to synthesize functional materials with redox activity, semiconductor properties, and high energy density under high pressure, and explore their applications in semiconductors, lithium batteries, catalysis, and energetic materials etc.

◆ Reaction mechanism

The reaction path of the polymerization under high pressure can be completely different with those happened under ambient pressure. We investigate the reaction mechanism by focus onthe crystal structures and the molecular structure before and after the reaction under high pressure, using crystallographic, optical and X-ray spectroscopic methods.

Abiotic gas formation and the carbon-hydrogen cycle process in the deep earth

The inside of the earth is a high temperature and high pressure environment. Subducting plates provide a rich source of carbon and hydrogen for the deep earth. Studying the interaction of these substances in the high temperature and high pressure environment of the earth and the physical and chemical processes will provide us with an important reference for understanding the carbon-hydrogen cycle inside the earth.

研究方向

极端条件下多维碳基、氮基材料的合成

◆利用高压等物理手段可控合成多维碳材料

我们利用高压并结合变温、光照等条件从小分子出发合成诸如金刚石纳米线、石墨烷、纳米石墨带等多维碳基、氮基材料并试图研究相关反应的控制规律，建立极端条件下碳基、氮基材料合成的系统方法，为材料结构的原子级可控合成提供高压方案。

◆功能材料的探索合成

高压是合成高密度修饰聚合物材料的有效手段。我们将尝试高压下具有氧化还原活性、半导体特性以及具有高能量密度等的功能材料的合成，并探索它们在半导体、锂电池、催化以及含能材料方面的应用。

◆反应机理

高压下，处于极端受限条件下的分子的化学反应规律完全不同于常压。我们利用原位的衍射、光谱学及化学微分析的方法并结合理论计算，研究总结在高压条件下特有的化学反应规律及过程。

非生物成气与地球深部的碳-氢循环过程

◆地球深部非生物气的形成与转化

地球内部是高温高压环境。俯冲板块为地球深部提供了丰富的碳源和氢源，研究这些物质在地球内部高温高压环境下的相互作用以及物理化学过程将为我们理解地球内部的碳-氢循环提供重要的参考。

Publications after joining HPSTAR:

加入北京高压科学研究中心后发表的论文：

[88] Qing Yang, Xinyi Yang*, Yixuan Wang, Yunfan Fei, Fang li, Haiyan Zheng, Kuo Li, Yibo Han, Takanori Hattori, Pinwen Zhu, Shuaiqiang Zhao, Leiming Fang, Xuyuan Hou, Zhaodong Liu, Bing Yang, Bo Zou*, Brightening triplet excitons enable high-performance white-light emission in organic small molecules via integrating n–π*/π–π* transitions, Nature Communications, 2024, 15, 7778 (2024).

[87] Yunfan Fei, Yapei Li, Puyi Lang, Xingyu Tang, Peijie Zhang, Guangwei Che, Xiao Dong, Kuo Li*, Haiyan Zheng*, High Pressure Polymerization of 2,6-Diethynylpyridine, The Journal of Physical Chemistry C, 2024

[86] 费云帆, 李阔, 郑海燕, 高压固相拓扑聚合合成纳米碳材料。高压物理学报 2023, 37 (6): 060101.

[85] Zhe Zhang^#, Kuo Li^#, Shangchao Lin*, Ruiqi Song, Dehong Yu, Yida Wang, Jingfan Wang,Shogo Kawaguchi, Zhao Zhang, Chenyang Yu, Xiaodong Li, Jie Chen, Lunhua He, Richard Mole, Bao Yuan, Qingyong Ren, Kun Qian, Zhuangli Cai, Jingui Yu, Mingchao Wang, Changying Zhao, Xin Tong, Zhidong Zhang,* Bing Li,* Science Advance 2023, 9, eadd0374.

[84] Shuhang Liu, Jun Han, Rongli Cui, Xin Yang, Yunfan Fei, Xingyu Tang, Yida Wang, Yajie Wang, Yongjin Chen, Jiajia Feng, Haiyan Zheng, Kuo Li,* Xiaoyang Liu,*  Gd-doped diamond synthesized by Gd@C82 under high pressure and high temperature.  Inorganic Chemistry Frontier, 2023,10, 5136-5143.

[83]Xingyu Tang, Xiao Dong,* Chunfang Zhang, Kuo Li,* Haiyan Zheng, Ho-kwang Mao, Triggering dynamics of acetylene topochemical polymerization. Matter and Radiation at Extremes, 2023, 8, 058402.

[82] Dexiang Gao, Xingyu Tang, Chunfang Zhang, Yajie Wang, Xin Yang, Peijie Zhang, Xuan Wang, Jingqin Xu, Jie Su, Fuyang Liu, Xiao Dong, Xiaohuan Lin, Bao Yuan, Nozomu Hiraoka, Haiyan Zheng,* Le Kang,* Kuo Li, and Ho-kwang Mao, Arylazo under Extreme Conditions: [2 + 2] Cycloaddition and Azo Metathesis. The Journal of Physical Chemistry C, 2023, 127, 8482-8492.

[81] Yida Wang, Guangwei Che, Xin Yang, Jie Zheng,*  Youyu Lin, Haiyan Zheng, Kuo Li,* and Ho-kwang Mao, Piezovoltaics from PdHx,  The Journal of Physical Chemistry Letters, 2023, 14, 3168−3173.

[80] Peijie Zhang, Dexiang Gao, Xingyu Tang, Xin Yang, Haiyan Zheng, Yida Wang, Xuan Wang, Jingqin Xu,Zijia Wang, Jie Liu, Xiaoge Wang, Jing Ju, Mingxue Tang, Xiao Dong, Kuo Li,* and Ho-kwang Mao, Ordered Van der Waals Hetero-nanoribbon from Pressure-Induced Topochemical Polymerization of Azobenzene.Journal of the American Chemical Society 2023, 145, 6845-6852.

[79] Xuan Wang, Xin Yang, Yida Wang, Xingyu Tang, Haiyan Zheng, Peijie Zhang, Dexiang Gao, Guangwei Che, Zijia Wang, Aijiao Guan, Jun-Feng Xiang, Mingxue Tang, Xiao Dong, Kuo Li,* and Ho-kwang Mao, From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid. Journal of the American Chemical Society 2022, 144, 21837−21842

[78] Xuan Wang, Xingyu Tang, Xin yang, Yida Wang, Peijie Zhang, Xiao Dong, Dongliang Yang, Xujie Lü, Haiyan Zheng, Kuo Li,* and Ho-kwang Mao, High-Pressure Synthesis of Highly Conjugated Polymers via Synergistic Polymerization of Phenylpropiolic Acid. ACS Applied Polymer Material 2022,  4, 5246–5252

[77] Peijie Zhang, Xingyu Tang, Chunfang Zhang, Dexiang Gao, Xuan Wang, Yajie Wang, Wenhan Guo, Ruqiang Zou, Yehua Han, Xiaohuan Lin, Xiao Dong, Kuo Li, Haiyan Zheng*, Ho-kwang Mao, Pressure-induced hydrogen transfer in 2-butyne via double CH∙∙∙π aromatic transition state.  The Journal of Physical Chemistry Letters 2022, 13, 4170−4175.

[76] Dexiang Gao, Xingyu Tang, Jingqin Xu, Xin Yang, Peijie Zhang, Guangwei Che, Yajie Wang, Yongjin Chen, Xiang Gao, Xiao Dong, Haiyan Zheng*, Kuo Li, Ho-kwang Mao*, Crystalline C₃N₃H₃ Tube (3,0) Nanothreads, Proceedings of the National Academy of Sciences of the United States of America (PNAS), 2022, 119 (17), e2201165119.

[75] Xuan Wang, Xingyu Tang, Peijie Zhang, Yida Wang, Dexiang Gao, Jie Liu, Kanglong Hui, Yajie Wang, Xiao Dong, Takanori Hattori, Asami Sano-Furukawa, Kazutaka Ikeda, Ping Miao, Xiaohuan Lin, Mingxue Tang, Zicheng Zuo, Haiyan Zheng*, Kuo Li and Ho-kwang Mao, Crystalline Fully Carboxylated Polyacetylene Obtained under High Pressure as a Li-Ion Battery Anode Material. The Journal of Physical Chemistry Letters 2021, 12, 12055–12061.

[74] Fang Li , Jingqin Xu , Yajie Wang *, Haiyan Zheng * and Kuo Li *, Pressure-Induced Polymerization: Addition and Condensation Reactions. Molecules 2021, 26, 7581 (Invited by Prof. Roberto Bini).

[73] Jianjun Mao, Yida Wang, Kuo Li* and Yue Chen*, Pressure-Enriched Chemistry of Pt: Prediction and Synthesis of Dense Sodium Platinides. The Journal of Physical Chemistry C 2021, 125, 11791–11798

[72] Yida Wang, Xin Yang, Xingyu Tang, Xuan Wang, Yapei Li, Xiaohuan Lin, Xiao Dong, Dongliang Yang, Haiyan Zheng, Kuo Li*, and Ho-kwang Mao, Pressure Gradient Squeezing Hydrogen out of MnOOH: Thermodynamics and Electrochemistry. The Journal of Physical Chemistry Letters 2021, 12, 10893–10898.

[71] Yapei Li, Xingyu Tang, Peijie Zhang, Yida Wang, Xin Yang, Xuan Wang, Kuo Li, Yajie Wang, Ningning Wu, Mingxue Tang, Junfeng Xiang, Xiaohuan Lin, Hyun Hwi Lee, Xiao Dong, Haiyan Zheng,* and Ho-kwang Mao, Scalable High-Pressure Synthesis of sp2−sp3 Carbon Nanoribbon via [4 + 2] Polymerization of 1,3,5-Triethynylbenzene. The Journal of Physical Chemistry Letters  2021, 12, 7140−7145.

[70] Dexiang Gao, Xingyu Tang, Xuan Wang, Xin Yang, Peijie Zhang, Guangwei Che, Jun Han, Takanori Hattori, Yajie Wang,  Xiao Dong,  Haiyan Zheng, * Kuo Li and  Ho-kwang Mao, Phase transition and chemical reactivity of 1H-tetrazole under high pressure up to 100 GPa.Physical Chemistry Chemical Physics, 2021, 23, 19503-19510.

[69] Peijie Zhang; Xingyu Tang; Yida Wang; Xuan Wang; Dexiang Gao; Yapei Li; Haiyan Zheng; Yajie Wang; Xinxin Wang; Riqiang Fu; Mingxue Tang; Kazutaka Ikeda; Ping Miao; Takanori Hattori; Asami Sano-Furukawa; Christopher A. Tulk; Jamie J. Molaison; Xiao Dong; Kuo Li; Jing Ju; Ho-kwang Mao, "Distance Selected” Topochemical Dehydro-Diels-Alder Reaction of 1,4-Diphenylbutadiyne towards Crystalline Graphitic Nanoribbons. Journal of the American Chemical Society, 2020, 142, 17662-17669.

[68] Xin Yang, Yapei Li, Yajie Wang, Haiyan Zheng,* Kuo Li, Ho-kwang Mao, Chemical transformations of n-hexane and cyclohexane under the upper mantle conditions. Geoscience Frontiers, 2020 ,12, 1010-1017.

[67] Zhijian Tan, Ping Miao,* Masato Hagihala, Sanghyun Lee, Yoshihisa Ishikawa, Shuki Torii, Masao Yonemura, Takashi Saito, Sihao Deng, Jie Chen, Lunhua He, Rong Du, Junrong Zhang, Haisheng Li, Junliang Sun, Yingxia Wang, Xiaohuan Lin, Kuo Li, and Takashi Kamiyama,* Room Temperature Zero Thermal Expansion in a Cubic Cobaltite. The Journal of Physical Chemistry Letters, 2020,11, 6785−6790.

[66] Junjie Guan, Xingyu Tang, Chunfang Zhang, Kuo Li, Xiaohuan Lin, Lin Wang, Hyun Hwi Lee, Jialiang Xu, Haiyan Zheng, Ho-Kwang Mao, The Consecutive and Extensive Transition of Luminescent Color of an Organic Solid Material by Applying the High Pressure. The Journal of Physical Chemistry C, 2020, 124, 14911−14917.

[65] Sheng Mei, Yu Guo, Xiaohuan Lin, Hao Dong, Ling-Dong Sun*, Kuo Li* and Chun-Hua Yan,* Experimental and Simulation Insights into Local Structure and Luminescence Evolution in Eu³⁺-Doped Nanocrystals under High Pressure. The Journal of Physical Chemistry Letters, 2020, 11, 3515–3520.

[64] Yarong Gu, Haichao Liu, Ran Qiu, Zhaodong Liu, Chunyu Wang, Tomoo Katsura, Hua Zhang, Min Wu, Mingguang Yao, Haiyan Zheng, Kuo Li, Yajie Wang, Kai Wang,* Bing Yang, Yuguo Ma, and Bo Zou, Pressure-Induced Emission Enhancement and Multicolor Emission for 1,2,3,4-Tetraphenyl-1,3-cyclopentadiene: Controlled Structure Evolution. The Journal of Physical Chemistry Letters,  2019, 10, 5557−5562.

[63] Jun Han, Xingyu Tang, Yida Wang, Yajie Wang, Yehua Han, Xiaohuan Lin, Xiao Dong, Hyun Hwi Lee, Haiyan Zheng,* Kuo Li,* and Ho-kwang Mao, Pressure-Induced Polymerization of Monosodium Acetylide: A Radical Reaction Initiated Topochemically. The Journal of Physical Chemistry C,  2019, 123, 30746-30753.

[62] Xiao Dong, Jingyu Hou, Jun Kong, Haixu Cui, Yan-Ling Li, Artem R. Oganov, Kuo Li, Haiyan Zheng, Xiang-Feng Zhou, and Hui-Tian Wang, Predicted lithium oxide compounds and superconducting low-pressure LiO₄, Physical Review B, 2019, 100, 144104.

[61] Xin Yang, Xuan Wang, Yida Wang, Kuo Li and Haiyan Zheng,* From Molecules to Carbon Materials—High Pressure Induced Polymerization and Bonding Mechanisms of Unsaturated Compounds. Crystals 2019, 9, 490.

[60] Fan Wang, Zicheng Zuo,* Liang Li, Kuo Li, Feng He, Zhongqing Jiang, Yuliang Li, *Large‐Area Aminated‐Graphdiyne Thin Films for Direct Methanol Fuel Cells. Angewandte Chemie International Edition, 2019, 58, 15010 -15015.

[59] Xuan Wang, Peijie Zhang, Xingyu Tang, Junjie Guan, Xiaohuan Lin, Yajie Wang, Xiao Dong, Binbin Yue, Jinyuan Yan, Kuo Li,* Haiyan Zheng,* Ho-kwang Mao, Structure and Electrical Performance of Na₂C₆O₆ under High Pressure. The Journal of Physical Chemistry C,  2019, 123, 17163−17169.

[58] 王萱,李阔,郑海燕,张沛捷, 分子体系的高压化学反应, 化学通报-中国化学会青年化学奖获奖者专栏，2019, 82, 387-398.

[57] Junjie Guan, Chunfang Zhang, Dexiang Gao, Xingyu Tang, Xiao Dong, Xiaohuan Lin, Yajie Wang, Xinxin Wang, Lin Wang, Hyun Hwi Lee, Jialiang Xu,* Haiyan Zheng,* Kuo Li and Ho-kwang Mao, Drastic photoluminescence modulation of an organic molecular crystal with high pressure. Materials Chemistry Frontiers, 2019, 3, 1510-1517.

[56] Hulei Yu , Xiaohuan Lin, Kuo Li* , and Yue Chen*, Unveiling a Novel, Cation-Rich Compound in a High-Pressure Pb–Te Binary System. ACS Central Science, 2019, 5, 683-687.

[55] Bing Li*, Yukinobu Kawakita, Seiko Ohira-Kawamura, Takeshi Sugahara, Hui Wang, Jingfan Wang, Yanna Chen, Saori I. Kawaguchi, Shogo Kawaguchi, Koji Ohara, Kuo Li, Dehong Yu, Richard Mole, Takanori Hattori, Tatsuya Kikuchi, Shin-ichiro Yano, Zhao Zhang, Zhe Zhang, Weijun Ren, Shangchao Lin, Osami Sakata, Kenji Nakajima, Zhidong Zhang, Colossal barocaloric effects in plastic crystals. Nature, 2019, 567, 506-510. 

[54] Dexiang Gao, Jin Huang, Xiaohuan Lin, Dongliang Yang, Yajie Wang*, Haiyan Zheng*, Phase transitions and chemical reactions of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine under high pressure and high temperature, RSC Advances, 2019, 9, 5825-5833.

[53]Yajie Wang, Xiao Dong, Xingyu Tang, Haiyan Zheng*, Kuo Li*, Xiaohuan Lin, Leiming Fang, Guang’ai Sun, Xiping Chen, Lei Xie, Craig L. Bull, Nicholas P. Funnell, Takanori Hattori Asami Sano-Furukawa, Jihua Chen, Dale K. Hensley, George Cody, Yang Ren, Hyun Hwi Lee, Ho-kwang Mao, Pressure-Induced Diels-Alder Reactions in C6H6‐C6F6 Cocrystal towards Graphane Structure, Angewandte Chemie International Edition, 2019, 58, 1468 –1473.

[52]Hulei Yu, Dexiang Gao, Xiancheng Wang, Xueyan Du, Xiaohuan Lin, Wenhan Guo, Ruqiang Zou, Changqing Jin, Kuo Li*, Yue Chen*, Unraveling a novel ferroelectric GeSe phase and its transformation into a topological crystalline insulator under high pressure, NPG Asia Materials, 2018, 10, 882–887.

[51]Xiao Dong, Lijuan Wang, Kuo Li*, Haiyan Zheng*, Yajie Wang, Yue Meng, Haiyun Shu, Ho-kwang Mao, Shaomin Feng, and Changqing Jin, Tailored Synthesis of the Narrowest Zigzag Graphene Nanoribbon Structure by Compressing the Lithium Acetylide under High Temperature, The Journal of Physical Chemistry C, 2018, 122, 20506-20512.

[50]H. Xiao, T. Hu, W. Liu, Y. L. Zhu, P. G. Li, G. Mu, J. Su, K. Li, and Z. Q. Mao, Superconductivity in the half-Heusler compound TbPdBi, Physical Review B, 2018, 97, 224511.

[49]Hong Shang, Zicheng Zuo, Haiyan Zheng, Kuo Li, Zeyi Tu, Yuanping Yi, Huibiao Liu, Yongjun Li, Yuliang Li, N-doped Graphdiyne for High-Performance Electrochemical Electrodes, Nano Energy 2018, 44, 144-154.

[48]Mufei Yue, Yajie Wang, Lijuan Wang, Xiaohuan Lin, Kuo Li*, Haiyan Zheng*, and Tao Yang, Pressure-induced polymerization of butyndioic acid and its Li+ salt, Chinese Chemical Letters 2018, 29, 328-330.

[47]Lijuan Wang, Xiao Dong, Yajie Wang, Haiyan Zheng*, Kuo Li*, Xing Peng, Ho-kwang Mao, Changqing Jin*, Yufei Meng, Mingquan Huang, and Zhisheng Zhao, Pressure induced polymerization and disproportionation of Li₂C₂ accompanied with irreversible conductivity enhancement,The Journal of Physical Chemistry Letters,  2017, 8, 4241−4245.

[46]Jiangman Sun, Xiao Dong, Yajie Wang, Kuo Li*, Haiyan Zheng*, Lijuan Wang, George D. Cody, Christopher A. Tulk, Jamie J. Molaison, Xiaohuan Lin, Yufei Meng, Changqing Jin, and Ho-kwang Mao, Pressure Induced Polymerization of Acetylene: Structure Directed Stereoselectivity and a Possible Route to Graphane, Angewandte Chemie International Edition, 2017, 56, 6553-6557.

[45]Z. L. Dun, J. Trinh, M. Lee, E. S. Choi, K. Li, Y. F. Hu, Y. X. Wang, N. Blanc, A. P. Ramirez, and H. D. Zhou, Structural and magnetic properties of two branches of the tripod-kagome-lattice family A₂R₃Sb₃O₁₄ (A = Mg, Zn; R = Pr, Nd, Gd, Tb, Dy, Ho, Er, Yb), Physical Review B, 2017, 95, 104439.

[44]Hulei Yu, Wenxin Lao, Lijuan Wang, Kuo Li*, and Yue Chen*, Pressure-stabilized tin selenide phase with an unexpected stoichiometry and a predicted superconducting state at low temperature,Physical Review Letters, 2017, 118, 137002.

[43]Xiao Dong, Artem R. Oganov, Alexander F. Goncharov, Elissaios Stavrou, Sergey Lobanov, Gabriele Saleh, Guang-Rui Qian, Qiang Zhu, Carlo Gatti, Volker L. Deringer, Richard Dronskowski, Xiang-Feng Zhou, Vitali Prakapenka, Zuzana Konôpková, Ivan Popov, Alexander I. Boldyrev, Hui-Tian Wang, A stable compound of helium and sodium at high pressure, Nature Chemistry, 2017, 9, 440-445.

[42]Haiyan Zheng, Lijuan Wang, Kuo Li*, Youyou Yang, YajieWang, Jiajia Wu, Xiao Dong, Chun-Hai Wang, Christopher A. Tulk, Jamie J. Molaison, Ilia N. Ivanov, Mikhail Feygenson, Wenge Yang, Malcolm Guthrie, Yusheng Zhao, Ho-Kwang Mao, Changqing Jin, Pressure induced polymerization of acetylide anions in CaC₂ and 10⁷ folds enhancement of electrical conductivity, Chemical Science, 2017, 8, 298-304.

[41]Haiyan Zheng, Kuo Li*, George Cody, Christopher A. Tulk, Xiao Dong, Guoying Gao, Jamie J. Molaison, Zhenxian Liu, Mikhail Feygenson, Wenge Yang, Ilia N. Ivanov, Leonardo Basile, Juan-Carlos Idrobo, Malcolm Guthrie,and Ho-kwang Mao, Polymerization of Acetonitrile via Hydrogen Transfer Reaction from CH₃ to CN under Extreme Condition, Angewandte Chemie International Edition, 2016, 55, 12040-12044.

[40]Yajie Wang, Lijuan Wang, Haiyan Zheng*, Kuo Li*, Michał Andrzejewski, Takanori Hattori, Asami Sano-Furukawa, Andrzej Katrusiak, Yufei Meng, Fuhui Liao, Fang Hong, and Ho-kwang Mao, Phase Transitions and Polymerization of C₆H₆−C₆F₆ Cocrystal under Extreme Conditions. The Journal of Physical Chemistry C, 2016, 120, 29510–29519.

[39]Ho-kwang Mao*, Bin Chen, Jiuhua Chen, Kuo Li, Jung-Fu Lin, Wenge Yang, Haiyan Zheng, Recent Advances in High-Pressure Science and Technology, Matter and Radiation at Extremes, 2016, 1, 59-75.

[38]Zhiling Dun, Jennifer Trinh, Kuo Li, Minseong Lee, Kuanwei Chen, Ryan Baumbach, Yufei Hu, Yingxia Wang, Eun Sang Choi, B. Sriram Shastry, Arthur P. Ramirez, Haidong Zhou, Removing the spin ice cap: magnetic ground states of rare earth tripod kagome lattice Mg₂RE₃Sb₃O₁₄ (RE = Gd, Dy, Er), Physical Review Letters,  2016, 116, 157201-157201.

[37]Jie Liang, Jie Su*, Yanping Chen, Zhaofei Li, Kuo Li, Hao Zhang, Xiaodong Zou, Fuhui Liao, Yingxia Wang*, Jianhua Lin*, Syntheses, structure solutions, and catalytic performance of two novel layered silicates, Dalton Transactions,  2015, 44, 15567-15575.

[36]Kuo Li*, Haiyan Zheng*, Takanori Hattori, Asami Sano Furukawa, Christopher A. Tulk, Jamie Molaison, Mikhail Feygenson, Ilia N. Ivanov, Wenge Yang, Ho-kwang Mao, Synthesis, Structure and Pressure Induced Polymerization of  Li₃Fe(CN)₆ Accompanied with Enhanced Conductivity, Inorganic Chemistry, 2015, 54, 11276–11282.

[35]Kuo Li*, Haiyan Zheng*, Lijuan Wang, Christopher A. Tulk, Jamie J. Molaison, Mikhail Feygenson, Wenge Yang, Malcolm Guthrie, Ho-kwang Mao, K₃Fe(CN)₆ under External Pressure: Dimerization of CN-Coupled with Electron Transfer to Fe(III), The Journal of Physical Chemistry C,  2015, 119, 22351–22356.

[34]Kuo Li, Yufei Hu, Yingxia Wang, Takashi Kamiyama, Bingwu Wang, Zhaofei Li, Jianhua Lin, Syntheses and properties of a family of new compounds RE₃Sb₃Co₂O₁₄ (RE=La, Pr, Nd, Sm-Ho) with an ordered pyrochlore structure, Journal of Solid State Chemistry, 2014, 217, 80–86.

[33]ChihChau Hwang, Gedeng Ruan, Lu Wang, Haiyan Zheng, Errol L. G. Samuel, Changsheng Xiang, Wei Lu, William Kasper, Kewei Huang, Zhiwei Peng, Zachary Schaefer, Amy T. Kan, Angel A. Martí, Michael S. Wong, Mason B. Tomson, and James M. Tour, Carbon-Based Nanoreporters Designed for Subsurface, Hydrogen Sulfide Detection, ACS Applied Materials & Interfaces, 2014, 6, 7652–7658.

[32]Kuo Li*, Haiyan Zheng, Ilia N. Ivanov, Malcolm Guthrie, Yuming Xiao, Wenge Yang, Chris A. Tulk, Yusheng Zhao, and Ho-kwang Mao, K₃Fe(CN)₆: Pressure-Induced Polymerization and Enhanced Conductivity, The Journal of Physical Chemistry C,  2013, 117, 24174-24180.

[31]Malcolm Guthrie, Reinhard Boehler, Christopher A. Tulk, Jamie J Molaison, António M Dos Santos, Kuo Li, Russell J Hemley, Neutron diffraction  observations of interstitial protons in dense ice, Proceedings of the National Academy of Sciences of the United States of America, 2013, 110, 10552-10556.

Publications before joining HPSTAR:

加入北京高压科学研究中心前发表的论文:

[30]Hui Wang, Chengxu Yang, Jun Lu, Meimei Wu, Jie Su, Kuo Li, Junrong Zhang, Guobao Li, Tounan Jin, Takashi Kamiyama, Fuhui Liao, Jianhua Lin, Yicheng Wu, On the Structure of α-BiFeO_3, Inorganic Chemistry, 2013, 52, 2388-2392.

[29]Yonggang Wang, Jie Liang, Ting Wen, Kuo Li, Yingxia Wang, Guobao Li, Fuhui Liao, Jianhua Lin, Syntheses and properties of a series of chromium vanadates ACrV₂O₇ (A=Na, K, Rb, Cs) with layered structure, Journal of Solid State Chemistry, 2012,192, 1–6.

[28]Qingxia Yao, Junliang Sun, Kuo Li, Jie Su, Maxim V Peskov, Xiaodong Zou, A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation, Dalton Transactions, 2012, 41, 3953-3955.

[27]Ganghua Zhang, Guobao Li, Fuqiang Huang, Fuhui Liao, Kuo Li, Yinxia Wang, Jianhua Lin, Hydrothermal synthesis of superconductors Ba1−xKxBiO3 and double perovskites Ba_1−xK_xBi_1−yNayO_3, Journal of Alloys and Compounds, 2011, 509, 9804–9808.

[26]Shiliang Huang, Kirsten Christensen, Maxim V Peskov, Sihai Yang, Kuo Li,  Xiaodong Zou, Junliang Sun, Two open-framework germanates with nickel complexes incorporated into the framework, Inorganic Chemistry, 2011, 50, 9921-9923.

[25]Kuo Li, Denis Sheptyakov, Yingxia Wang, Chun-Keung Loong, Jianhua Lin, Phase diagram of SrO–InO_1.5–CoO_x and a new compound Sr3In0.9Co1.1O6, Journal of Solid State Chemistry 2011, 184, 888–892.

[24]Kuo Li, Yingxia Wang, Jianhua Lin, Zhaofei Li, Phase relations of BaCoO_3-δ-BaInO_2.5 and size variation effect of B-site cations on the phase transitions, Solid State Ionics, 2011, 183, 7–15.

[23]Min Yang, Kuo Li, Jie Su, Q. Huang, Wei Bao, Liping You, Zhaofei Li, Yingxia Wang, Yu Jiang, Fuhui Liao, Jianhua Lin, Study on the crystal structure of  the rare earth oxyborate Yb₂₆B₁₂O₅₇ from  powder X-ray and neutron diffraction, Journal of Alloys and Compounds, 2011, 509, 4707-4713.

[22]Haiyan  Zheng, Yuliang Li*, Chunjie Zhou, Yongjun Li*, Wenlong Yang, Weidong Zhou,  Zicheng Zuo, Huibiao Liu, Synthesis of [2]Rotaxane Incorporating "Magic Ring" Via Thiol-Ene Click Reaction, Chemistry – A European Journal, 2011, 17 , 2160-2167.

[21]Haiyan  Zheng, Yongjun Li*, Huibiao Liu, Xiaodong Yin and Yuliang Li*, Architecture  Heterostructure Materials toward the Novel Properties Construction of  Heterostructure Materials toward Functionality Chemical Society Reviews,  2011, 40, 4506-4524.

[20]Jing Lv, Xiaodong Yin, Haiyan Zheng, Yongjun Li, Yuliang Li*, Daoben Zhu, The configuration solvatochromism and metallo-responses of two novel cyano-containing oligo (phenylene-vinylene) derivatives, Luminescence, 2011, 26, 185-190.    

[19]Kuo Li, Yingxia Wang, Jie Su, Jianhua Lin, Syntheses, Structures and Properties of Hemi-Hydrogarnet Sr₆Sb₄M₃O₁₄(OH)₁₀ (M=Co, Mn), Acta Physico - Chimica Sinica,  2010, 26, 1823-1831.  

[18]Rihong Cong, Tao Yang, Kuo Li, Hongmei Li, Liping You, Fuhui Liao, Yingxia  Wang, Jianhua Lin, Mullite-type Ga₄B₂O₉: structure and order-disorder phenomenon, Acta crystallographica. Section B-Structural Science, 2010, 66, 141-150.  

[17]Weidong Zhou, Haiyan Zheng, Yongjun Li*, Huibiao Liu and Yuliang Li*, Synthesis of Sulfuric Macrocycles and a Rotaxane through Thiol-yne Click and  Dithiol Coupling Reactions, Organic Letters 2010, 12, 4078-4081.

[16]Jialiang Xu, Haiyan Zheng, Huibiao Liu*, Chunjie Zhou, Yingjie Zhao, Yongjun  Li and Yuliang Li*, Crystal Hierarchical  Supramolecular Architectures from 1-D Precursor Single-Crystal Seeds, The Journal of Physical Chemistry C,  2010, 114, 2925-2931.

[15]Yingjie Zhao, Yuliang Li*, Yongjun Li*, Haiyan Zheng, Xiaodong Yin, Huibiao  Liu, Construction of an interpenetrated structure of macrocycles, Chemical Communications, 2010, 46, 5698-5700.

[14]Xiaofeng Liu, Huibiao Liu, Weidong Zhou, Haiyan, Zheng, Xiaodong Yin, Yuliang Li*, Yanbing Guo, Mei Zhu, Canbin Ouyang, Daoben Zhu,Andong Xia, Thermoreversible Covalent Self-Assembly of Oligo (p-phenylenevinylene) Bridged Gold Nanoparticles, Luminescence, 2010, 26, 3179-3185.

[13]Wei Bao, Y. X. Wang, Y. Qiu, K. Li, J H Lin, J. R. D. Copley, R. W. Erwin, B.  S. Dennis, A. P. Ramirez: Spin Order andExcitations in Triangular  Antiferromagnet La₂Ca₂MnO₇, 2009, arXiv:0910.1904

[12]Haiyan Zheng, Weidong Zhou, Mingjian Yuan, Xiaodong Yin, Zicheng Zuo, Canbin Ouyang, Huibiao Liu, Yuliang Li*, Optic and Proton dual-control of the Fluorescence  of Rhodamine Based on Photochromic Diarylethene: Mimicking the Performance of  an Integrated Logic Gate, Tetrahedron Letters, 2009, 50, 1588-1592.  

[11]Haiyan  Zheng, Weidong Zhou, Jing Lv, Xiaodong Yin, Yongjun Li, Huibiao Liu, Yuliang  Li*, A Dual-Response [2]Rotaxane Based on a 1, 2, 3- Triazole Ring as a Novel Recognition Station,Chemistry – A European Journal, 2009, 15, 13253-13262.  

[10]Mingjian Yuan, Xiaodong Yin, Haiyan Zheng, Canbin Ouyang, Zicheng Zuo,  Huibiao Liu, Yuliang Li*, Light Harvesting and Efficient Energy Transfer in  Dendritic Systems: New Strategy for Functionalized Near-Infrared BF₂-Azadipyrromethenes, Chemistry – An Asian Journal, 2009, 4, 707-713.  

[9]Weidong Zhou, Jialiang Xu, Haiyan Zheng, Xiaodong Yin, Zicheng Zuo, Huibiao  Liu, Yuliang Li*, Distinct Nanostructures from aMolecular Shuttle: Effects  of Shuttling Movement on Nanostructural Morphologies, Advanced Functional Materials, 2009, 19, 141-149.

[8]Zicheng Zuo, Huibiao Liu, Xiaodong Yin, Haiyan Zheng, Yuliang Li, Controllable growth of one-dimensional chiral nanostructures from an achiral molecule, Journal of Colloid and Interface Science, 2009, 329, 390-394.

[7]Weidong Zhou, Jialiang Xu, Haiyan Zheng, Huibiao Liu, Yuliang Li*, Daoben  Zhu, Charge Transfer Chromophore-Stopped [2]Rotaxane through [2 + 2] Cycloaddition, Journal of Organic Chemistry, 2008, 73, 7702-7709.

[6]Cuihong Li, Chunjie Zhou, Haiyan Zheng, Xiaodong Yin, Zicheng Zuo, Huibiao Liu, Yuliang Li*, Synthesis of a novel poly(para-phenylene ethynylene for highly selective and sensitive sensing mercury (II) ions,  Journal of Polymer Science Part A: Polymer Chemistry, 2008, 46, 1998-2007.

[5]Jing Lv, Canbin Ouyang, Xiaodong Yin, Zuo,Haiyan Zheng,Zicheng Zuo, Jialiang Xu, Huibiao Liu, Yuliang Li*, Reversible and Highly Selective Fluorescent Sensor for Mercury(II) Based on a Water-Soluble Poly(para-phenylene)s Containing Thymine and Sulfonate Moieties, Macromolecular Rapid Communications, 2008, 29, 1588-1592.

[4]Junbo Li, Weidong Zhou, Yuliang Li*, Huibiao Liu, Canbin Ouyang, Xiaodong Yin, Haiyan Zheng, Zicheng Zuo, Tunable threading/dethreading efficiency of the pseudorotaxane by ether chain length, Tetrahedron Letters,   2008, 49, 4857-4861.

[3]Mingjian Yuan, Weidong Zhou, Xiaofeng Liu, Mei Zhu, Junbo Li, Xiaodong Yin, Haiyan Zheng, Zicheng Zuo, Canbin Ouyang, Huibiao Liu, Yuliang Li*, DaobenZhu, A multianalyte chemosensor on a single molecule: promising structure for an integrated logic gate. Journal of Organic Chemistry, 2008, 73, 5008-5014.

[2]Mei Zhu, Li Jiang, Mingjian Yuan, Xiaofeng Liu, Canbin Ouyang, Haiyan Zheng, Xiaodong Yin, Zicheng Zuo, Huibiao Liu, Yuliang Li*, Efficient tuning nonlinear optical properties: synthesis and characterization of a series of novel poly(aryleneethynylene)s co-containing BODIPY, Journal of Polymer Science Part A: Polymer Chemistry, 2008, 46, 7401-7410.

[1]Yongjun Li, Haiyan Zheng, Yuliang Li*, Shu Wang, Ziyu Wu, Peng Liu, Zengqiang  Gao, Huibiao Liu, and Daoben Zhu, Photonic Logic Gates Based on Control of FRET by a Solvatochromic Perylene Bisimide, Journal of Organic Chemistry, 2007, 72, 2878-2885.

人才招聘　　 

招聘岗位：博士后

我们的团队从事有机化学，无机化学，固体化学、材料化学及计算化学与高压领域的多学科交叉研究。主要聚焦于几万到几十万大气压下的化学反应。一方面是以能源与环境问题为背景，研究简单含碳小分子的高压反应机理，另一方面是以电池材料为背景，研究用高压手段合成高电子、离子电导率的材料。两方面在固体有机、聚合物、固体无机、碳材料方向还有延伸。此外，还有高压中子衍射技术方向。

工作的主要特色就是一个字：新。研究的是新反应，合成的是新材料。极端条件是地学研究的手段，近年被拿来做物理，出了硫化氢高温超导等一批好工作，然而在化学方面的工作还比较少——尽管如此，也有一些革命性的工作发在顶级期刊上了。相比于化学的广阔天地，已有的工作还只是星星之火，期待更多更深入的研究。

希望招聘乐于探索，潜心学术的博士后。博士后的工作内容可以在上述方向之中根据个人的兴趣和特长选定。我们组的主要工作地点在北京，也会经常全世界范围内出差，用大科学装置做实验。如果是选择中子方向，可能常驻海外。

招聘要求：

具有无机化学，固体化学、有机化学、计算化学或材料科学及相关领域的研究经历。

具有以下背景或技能之一（多多益善）的博士优先：
1、晶体学
2、有机合成，反应机理研究、产物分析等
3、石墨烯及碳材料
4、高压
5、电池

不熟悉高压没关系。当你做腻了原有的方向，觉得自己可能被机器人淘汰的时候，为什么不来尝试一下新方向呢？

年薪：

年薪20-30万元可谈，解决北京市户口。

申请材料：

有意者请将个人简历（英文）、研究计划（英文）、及三封专家推荐信发送至李阔老师邮箱likuo@hpstar.ac.cn或郑海燕老师邮箱zhenghy@hpstar.ac.cn， 若有任何疑问，欢迎随时通过邮件与我们联系。

联合培养项目：

欢迎有化学及相关领域背景的同学们申请高科中心联合培养硕士及博士研究生

硕士、博士招生：

欢迎有相关领域背景的同学们来我们高科中心学习

以下是我们进行研究的几个专题方向：

1.应用高压技术合成新型锂电池正极材料,使用前所未有的方法去探索发现新型材料;

2.研究高压条件下的有机化学反应过程，发现高压下特有的反应过程；通过控制温度、压力、光照等条件合成具有新结构和性质的碳材料；

3.高压条件下飞秒光化学,探究极端条件下的化学反应过程;

4.你所感兴趣的任何高压化学相关的重要专题方向；

Postdoctoral Research Associate:

We have New Postdoctoral Positions available in HPSTAR. 

Our team is the muti disciplinary research group in areas of Organic Chemistry, Inorganic Chemistry, Solid State Chemistry, 

Material Chemistry and Computational Chemistry coupled with High Pressure. 

Qualification:

Interested applicants in Organic Chemistry, Inorganic Chemistry, Solid State Chemistry, Computational Chemistry,

Materials Science and related fields are welcome to apply. 

Annual Salary: 

In line with the HPSTAR standard (200,000-300,000 RMB).

Application: 

Please send your CV, research plans and list of references (three) in English to Dr. Kuo Li (likuo@hpstar.ac.cn) or 

Dr. Haiyan Zheng (zhenghy@hpstar.ac.cn)! Please feel free to Email Kuo or Haiyan for any questions. We are glad to answer.

Students of Joint Programs:

Students of Joint Programs in Chemistry and related fields are welcomed to apply HPSTAR for collaboration!

Master and Ph.D. Students:　　

New Ph.D. and master students in related fields are being recruited. You are welcomed to apply HPSTAR for your next degree.

Following are several selected topics that we are planning to investigate. 

1. Synthesizing novel cathode materials for Li-battery with high pressure techniques. Use the never-been-used method to search the 

    never-been-found material.

2. High pressure chemistry reaction mechanism target to synthesize the carbon materials with novel structure and properties.  

    Use the method of chemists' to solve the problem of  high pressure scientists.

3. Femtosecond photochemistry under high pressure. Find out what reaction is happening under extreme conditions.

4. Important topics related with high pressure chemistry that you are interested in!